A analysis workforce at Rice College led by James Tour, the T.T. and W.F. Chao Professor of Chemistry and professor of supplies science and nanoengineering, is tackling the environmental difficulty of effectively recycling lithium ion batteries amid their growing use.
The workforce has pioneered a brand new technique to extract purified energetic supplies from battery waste as detailed within the journal Nature Communications on July 24. Their findings have the potential to facilitate the efficient separation and recycling of beneficial battery supplies at a minimal price, contributing to a greener manufacturing of electrical automobiles (EVs).
“With the surge in battery use, particularly in EVs, the need for developing sustainable recycling methods is pressing,” Tour mentioned.
Typical recycling methods sometimes contain breaking down battery supplies into their elemental varieties by way of energy-intensive thermal or chemical processes which are expensive and have vital environmental impacts.
The workforce proposed that magnetic properties might facilitate the separation and purification of spent battery supplies.
Their innovation makes use of a way often known as solvent-free flash Joule heating (FJH). This system devised by Tour entails passing a present by way of a reasonably resistive materials to quickly warmth and remodel it into different substances.
Utilizing FJH, the researchers heated battery waste to 2,500 Kelvin inside seconds, creating distinctive options with magnetic shells and steady core buildings. The magnetic separation allowed for environment friendly purification.
Throughout the course of, the cobalt-based battery cathodes—sometimes utilized in EVs and related to excessive monetary, environmental and social prices—unexpectedly confirmed magnetism within the outer spinel cobalt oxide layers, permitting for straightforward separation.
The researchers’ strategy resulted in a excessive battery metallic restoration yield of 98% with the worth of battery construction maintained.
“Notably, the metal impurities were significantly reduced after separation while preserving the structure and functionality of the materials,” Tour mentioned. “The bulk structure of battery materials remains stable and is ready to be reconstituted into new cathodes.”
Rice graduate college students Weiyin Chen and Jinhang Chen in addition to postdoctoral researcher and Rice Academy Junior Fellow Yi Cheng are the co-lead authors of the research.
Extra data:
Weiyin Chen et al, Nondestructive flash cathode recycling, Nature Communications (2024). DOI: 10.1038/s41467-024-50324-x
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